F-Block Elements MCQ Assignment 4 - ChemContent

Vijay Ishwar
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10 F-Block Elements MCQ Questions are given on this page. These questions have been asked in previous year exams of CSIR NET, GATE, TIFR, BARC etc. Test your knowledge by trying these simple MCQs and match your answers with the answer key provided at the bottom of the page. 

Also note, you can attempt this assignment as a quiz where you can mark options, calculate your score and see which questions you attempted were correct and which were not. For doing so, go to Quiz link. To download the assignment in PDF format, click PDF.

Good Luck! 😊😉

Quiz        PDF

Q1 The strongest reducing ion of the following is

[GATE 2001]

         (a) U3+

         (b) Am3+

         (c) Cm3+

         (d) Cf3+

Q2 The lanthanide complex that do not have square antiprismatic structure is (acac = acetylacetonate; phen=1,10-phenanthroline)

[GATE 2005]

         (a) [Ce(NO3)6]2-

         (b) [La(acac)3(H2O)2]

         (c) [Ce(acac)4]

         (d) [Eu(acac)3(phen)]

Q3 The metal ion that is expected to shift the C1-methylene group in heptanol from 2 to 10 ppm in 1H NMR is

[GATE 2006]

         (a) Eu(III)

         (b) Tl(III)

         (c) Al(III)

         (d) Sc(III)

Q4 The difference in the measured and calculated magnetic moments (based on spin-orbit coupling) is observed for

[GATE 2007]

         (a) Pm3+

         (b) Eu3+

         (c) Dy3+

         (d) Lu3+

Q5 The separation of trivalent lanthanide ions, Lu3+, Yb3+, Dy3+, Eu3+, can be effectively done by a cation exchange resin using ammonia o-hydroxy isobutyrate as the event the order in which the ions will be separated is

[GATE 2007]

         (a) Lu3+, Yb3+, Dy3+, Eu3+

         (b) Eu3+, Dy3+, Yb3+, Lu3+

         (c) Dy3+, Yb3+, Eu3+, Lu3+

         (d) Yb3+, Dy3+, Lu3+, Eu3+

Q6 The calculated and observed magnetic moments differ considerably for an Aqua complex of Lanthanide (III) ion as a result of low-lying states of high J. The ion, among the following is

[GATE 2016]

         (a) Ce3+

         (b) Pr3+

         (c) Eu3+

         (d) Yb3+


 

Q7 The lanthanide ion that exhibits colour in its' aqueous solution is

[GATE 2017]

         (a) La(III)

         (b) Eu(III)

         (c) Gd(III)

         (d) Lu(III)

Q8 Generally, the coordination number and the nature of the electronic absorption band (f-f transition) of lanthanide (III) ion in their complexes are, respectively

[GATE 2018]

         (a) greater than 6 and sharp

         (b) 6 and broad

         (c) less than 6 and sharp

         (d) greater than 6 and broad

Q9 Which of the following dipositive lanthanide ion is most stable

         (a) Ce2+

         (b) Eu2+

         (c) Gd2+

         (d) Ho2+

Q10 The increasing order of basic character of hydroxides of Ln3+ ions is

         (a) La(OH)3, Nd(OH)3, Pr(OH)3, Gd(OH)3

         (b) Gd(OH)3, Nd(OH)3, Pr(OH)3, La(OH)3

         (c) Nd(OH)3, Pr(OH)3, Gd(OH)3, La(OH)3

         (d) Gd(OH)3, Nd(OH)3, La(OH)3, Pr(OH)3

Ans Key

1.a  2.a  3.a  4.b  5.a  6.c  7.b  8.a 9.b 10.b

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